Search results for "spectroscopic [binaries]"

showing 9 items of 29 documents

Combining HR-MAS and In Vivo MRI and MRSI Information for Robust Brain Tumor Recognition

2009

In this study we propose to classify short echotime brain MRSI data by using multimodal information coming from magnetic resonance imaging (MRI), magnetic resonance spectroscopic imaging (MRSI) and high resolution magic angle spinning (HR-MAS), and to develop an advanced pattern recognition method that could help clinicians in diagnosing brain tumors. We study the impact of using HR-MAS information in combination with in vivo information for classifying brain tumors and we investigate which parameters influence our classification results.

PhysicsNuclear magnetic resonancemedicine.diagnostic_testIn vivoPattern recognition (psychology)medicineMagic angle spinningBrain tumorHigh resolutionMagnetic resonance spectroscopic imagingMagnetic resonance imagingmedicine.disease
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High Energy, High Resolution X-Ray Spectroscopy: Microcalorimeters For Nuclear Line Astrophysics

2005

We introduce focusing optics and microcalorimeter spectroscopy to nuclear line emission astrophysics with a balloon payload concept called, B‐MINE. It is designed to probe the deepest regions of a supernova explosion by detecting 44Ti emission at 68 keV with spatial and spectral resolutions that are sufficient to determine the velocity distribution of the 44Ti emitting region. B‐MINE has a thin plastic foil telescope multilayered to maximize the reflectivity in a 20 keV band centered at 68 keV and a microcalorimeter array optimized for the same energy band. This combination provides a reduced background, an energy resolution of 50 eV and a 3σ sensitivity in 106 s of 6 × 10−8 ph cm−2 s−1 at …

PhysicsX-ray spectroscopySpectrometerPhysics::Instrumentation and Detectorsbusiness.industryAstrophysics::High Energy Astrophysical PhenomenaResolution (electron density)Astrophysicslaw.inventionTelescopeSupernovaOpticslawEmission spectrumSpectroscopybusinessX- and gamma-ray telescopes and instrumentation Photometric polarimetric and spectroscopic instrumentationLine (formation)
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Comprehensive Study on the Performance of Waste HDPE and LDPE Modified Asphalt Binders for Construction of Asphalt Pavements Application

2022

This research is aimed at investigating the mechanical behavior of the bitumen by the addition of high-density polyethylene (HDPE) and low-density polyethylene (LDPE) obtained from waste plastic bottles and bags. Polymers (HDPE and LDPE) with percentages of 0%, 2%, 4%, and 6% in shredded form by weight of bitumen were used to evaluate the spectroscopic, structural, morphological, and rheological properties of polymer-modified binders. The rheological properties for different factors; viscosity (ἠ) from Rotational Viscometer (RV), rutting factor G*/Sin (δ), fatigue characteristics G*. Sin (δ), for the modified binder from dynamic shear rheometer (DSR), Short and long-term a…

Polymers and Plasticswaste polyethyleneXRDcreep analysiSEMspectroscopic analysimorphological analysiGeneral Chemistrywaste polyethylene; spectroscopic analysis; morphological analysis; XRD; creep analysis; SEMPolymers
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Clerodane diterpenoids from Salvia splendens.

2006

Four new clerodane diterpenoids, salvisplendins A-D (1-4), have been isolated from an acetone extract of the flowers of SalVia splendens, together with an artifact (5), arising from salvisplendin D (4) by addition of diazomethane, and the already known clerodane olearin (6). The structures of the new compounds (1-5) were established mainly by 1D and 2D NMR spectroscopic studies and, in the case of salvisplendin A (1), by chemical correlation with splenolide B (7). Complete 1H and 13C NMR assignments for olearin (6), not published hitherto, are also reported.

StereochemistryPharmaceutical ScienceFlowersSalviaAnalytical ChemistryDiterpenes Clerodanechemistry.chemical_compoundFour new clerodane diterpenoids salvisplendins A-D (1-4) have been isolated from an acetone extract of the flowers of SalVia splendens together with an artifact (5) arising from salvisplendin D (4) by addition of diazomethane and the already known clerodane olearin (6). The structures of the new compounds (1-5) were established mainly by 1D and 2D NMR spectroscopic studies and in the case of salvisplendin A (1) by chemical correlation with splenolide B (7). Complete 1H and 13C NMR assignments for olearin (6) not published hitherto are also reportedDrug DiscoveryOrganic chemistrySalviaNuclear Magnetic Resonance BiomolecularPharmacologychemistry.chemical_classificationPlants MedicinalbiologyMolecular StructureChemistryDiazomethaneOrganic ChemistryCarbon-13 NMRbiology.organism_classificationChemical correlationTerpenoidComplementary and alternative medicineItalyMolecular MedicineDiterpeneTwo-dimensional nuclear magnetic resonance spectroscopyLactoneJournal of natural products
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La pittura vascolare attica a fondo bianco: la prospettiva archeologica, l'apporto dell'indagine scientifica

2017

Il presente contributo intende offrire nuovi spunti di ricerca sui vasi attici a fondo bianco e sulla relativa tecnica pittorica. In particolare, è stato selezionato come caso di studio il cratere del Pittore della Phiale (450-440 a.C.) con il mito di Perseo e Andromeda, esposto nel Museo Archeologico di Agrigento. La prima parte del lavoro si concentra sugli aspetti archeologici e storico-artistici, cercando di ricostruire il ruolo di questa tecnica nella produzione figurativa dell’artigiano e il rapporto tra il cratere di Agrigento e gli altri prodotti del Pittore della Phiale. Inoltre, viene considerata la connessione tra tecnica e con- testo di utilizzo e acquirenti o “committenti”, la…

Tecnica a fondo bianco Agrigento Pittore della Phiale analisi spettroscopiche fluoriescenza a raggi X TR-FTIR.Settore L-ANT/07 - Archeologia ClassicaWhite-ground technique Agrigento Phiale Painter spectroscopic analysis X-ray fluorescence TR-FTIRSettore CHIM/02 - Chimica Fisica
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Clusterization and Strong Coulpled-Channels Effects in Deuteron Interaction with 9Be Nuclei

2019

Angular distributions of protons, deuterons, tritons and alphaparticles emitted in the d + 9Be reaction at Elab=19.5 and 35.0 MeV have been measured. The elastic scattering channel is analysed in the framework of both the Optical Model and the Coupled-Channel approach. The interaction potential of the d + 9Be system is calculated in the framework of the Double-Folding model using the α + α + n three-body wave function of the 9Be nucleus. The (d, p) and (d, t) one-nucleon-transfer reactions are analysed within the coupledreaction-channel approach. The spectroscopic amplitudes for the different nuclear cluster configurations are calculated. Differential cross sections for the reaction channel…

double foldingelastic and inelastic scatteringNuclear Theoryoptical modelDWBAfew-nucleon transfer reactionshiukkasfysiikkaNuclear Experimentydinfysiikkaspectroscopic amplitudescluster structureCRC
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Fusingin vivoandex vivoNMR sources of information for brain tumor classification

2011

In this study we classify short echo-time brain magnetic resonance spectroscopic imaging (MRSI) data by applying a model-based canonical correlation analyses algorithm and by using, as prior knowledge, multimodal sources of information coming from high-resolution magic angle spinning (HR-MAS), MRSI and magnetic resonance imaging. The potential and limitations of fusing in vivo and ex vivo nuclear magnetic resonance sources to detect brain tumors is investigated. We present various modalities for multimodal data fusion, study the effect and the impact of using multimodal information for classifying MRSI brain glial tumors data and analyze which parameters influence the classification results…

medicine.diagnostic_testComputer sciencebusiness.industryApplied MathematicsMultimodal dataBrain tumorMagnetic resonance spectroscopic imagingMagnetic resonance imagingPattern recognitionmedicine.diseaseNuclear magnetic resonanceIn vivomedicineMagic angle spinningBrain magnetic resonance imagingArtificial intelligencebusinessInstrumentationEngineering (miscellaneous)Ex vivoMeasurement Science and Technology
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Differentiation between brain metastases and glioblastoma multiforme based on MRI, MRS and MRSI

2009

Brain metastases and glioblastoma multiforme are the most aggressive and common brain tumours in adults and they require a different clinical management. Anatomical magnetic resonance imaging (MRI) or clinical history, cannot always clearly distinguish between them. This study describes and verifies the use of magnetic resonance spectroscopy (MRS) and magnetic resonance spectroscopic imaging (MRSI) in combination with MRI for differential diagnosis of glioblastomas and metastases. Feature selection methods are applied to the magnetic resonance (MR) spectra of 121 patients and relevant features are detected. Different classification methods are used to distinguish glioblastoma multiforme and…

medicine.medical_specialtymedicine.diagnostic_testbusiness.industryMagnetic resonance spectroscopic imagingMagnetic resonance imagingmedicine.diseaseMetastasisClinical historymedicineRadiologyDifferential diagnosisMr imagesbusinessBrain metastasisGlioblastoma
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Zn2+ and Cu2+ complexes of a fluorescent scorpiand-type oxadiazole azamacrocyclic ligand: crystal structures, solution studies and optical properties

2020

A ligand comprised of a macrocyclic pyridinophane core having a pendant arm containing a secondary amine group linked through a methylene spacer to a pyridyl–oxadiazole–phenyl (PyPD) fluorescent system has been prepared (L). The crystal structures of [ZnL](ClO4)2 and [CuL](ClO4)2 show that M2+ is coordinated to all the nitrogen atoms of the macrocyclic core, the secondary amine of the pendant arm and the nitrogen atom of the pyridine group of the fluorescent moiety, the latter bond being clearly weaker than the one with the pyridine of the macrocycle. Solution studies showed the formation of a highly stable Cu2+ complex with 1 : 1 stoichiometry, whereas with Zn2+ least stable complexes were…

metal coordinationspectroscopic behaviourLigandzincOxadiazoleCrystal structureFluorescenceInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryPyridineMoietyAzacyclophanes oxadiazole scorpiand metal coordination zinc spectroscopic behaviourAmine gas treatingMethyleneAzacyclophanesoxadiazolescorpiandDalton Transactions
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